Creating instruments and voices
Can instruments and voices be created from existing instruments? How are ranges set? Are instrument XML files available on the internet?
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Are there particular instruments you'd like to see added? Have you checked under "All instruments" to be sure they aren't already there?
If you do need to add some, you can indeed create your own XML file based on the one that comes with MuseScore. See Edit / Preferences / Score to use your custom file. Or you can simply right click the staff for an existing instrument and use Staff Properties to change the range, etc. Use the View / Mixer to select a different sound, View / Synthesizer to load a whole new soundfont.